1 Basic Concepts of Chemistry
Specific volume of cylindrical virus particle is 6.02 × 10-2 cc/gm whose radius and length are 7 Å and 10 Å respectively. If NA= 6.02 ×1023, find molecular weight of virus. 1) 15.4 kg/mol 2) 1.54 × 104 kg/mol 3) 3.08 × 104 kg/mol 4) 3.08 × 103 kg/mol
Solution
1 Å = 10-10 m Volume of virus = πr2h = π ×(7×10-10)2× 10×-10 cc = 1.54×10-27 m3 6.02× 10-2 cc = 1 g Or 6.02 × 10-8 m3 = 10-3 kg ∴ weight of 1.54 × 10-27 m- = w W is the weight of one virus ∴molecular weight M of virus = w ×NA
2 Alcohols Phenols and Ethers
Phenol is most easily soluble in 1. sodium carbonate solution 2. sodium hydroxide solution 3. dilute HCl 4. both sodium hydroxide and dilute HCl
3 Basic Principles of Organic Chemistry
The maximum number of isomers (including stereoisomers) that are possible on monochlorination of the following compound, is 1) 4 2) 7 3) 6 4) 8
SOLUTION
Three chiral carbon ∴ 23 = 8 isomers
4 Solutions
The rate constant for a second order reaction is 8×10−5M−1 min−1. How long will it take a 1M solution to be reduced to 0.5M?
1) 8.66 × 103 minute 2) 8×10−5 minute 3) 1.25×104 minute 4) 4×10−5 minute
=> a = 1 M
=> K = 8 × 10-5 Mol-1min-1
So ,
The required t½ = 1/{1×8×10-5}
= 12500 min = 1.25×10? min
5 Haloalkanes and Haloarenes
The compound if contains an even number 'n' of chiral carbons, but the molecule can be divided into two equal and si,ilar halves , then how many optical active form it will have : 1) 2n 2) 2(n−1) 3) 2(n−1)/2 4) 2(n−1)−2(n−1)/2
6 Electrochemistry
In electro-refining of copper some gold is deposited as :
1) Electrolyte 2) Cathode 3) Cathode mud 4) Anode mud
7 General Principles & Process of Isolation of Metals
Which of the following ore is best concentrated by froth flotation method ? 1) Galena 2) Cassiterite 3) Magnetite 4) none
Galena (PbS) are sulphide ores. Cassiterite SnO2 (oxide ore), and Magnetite Fe3O4 (oxide ore) are not sulphide ore. The froth flotation process is used to concentrate sulphide ores, based on preferential wetting properties with frosting agent and water.
8 Atomic Structure
Consider the following statements,. the d-orbitals have (i) four lobes and two nodes (ii) four lobes and one node (iii)same sign in opposite lobs (iv)opposite sign in the opposite lobs 1) i alone 2) i and iii 3) ii and iii 4) i and iv
d-orbital have four lobes and two nodes and opposite lobes have the same sign
9 S – Block Elements
Alkaline earth metals have only positive oxidation state. This is due to their:
1) high melting points 2) high electronegativity 3) softness 4) low ionization potential
The alkaline earth metals have very low ionization energies. So, they easily lose electrons to form positively charged ions (cations).
10 Stoichiometry
When 0.5g. of sulphur is burnt to SO2 4.6 kj of heat is liberated. What is the enthalpy of formation of sulphur dioxide? (S=32 and O=16)
1) -147.2KJ 2) + 147.2KJ 3) + 294.4KJ 4) - 294.4KJ.
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